مطالعه اثر روش تهیه کاتالیست در کاهش بنزن موجود در پلاتفرمیت پالایشگاهی با استفاده از هیدروژناسیون رقابتی

نوع مقاله : ترویجی

نویسندگان

1 دانشگاه شهید بهشتی، دانشکده علوم شیمی و نفت، گروه شیمی فیزیک، تهران

2 هیئت علمی/دانشکده شیمی دانشگاه شهید بهشتی

3 شرکت ملی پالایش و پخش فرآورده‌های نفتی ایران

چکیده

کاتالیستهای نیکل با روشهای مختلفی تهیه و برای هیدروژناسیون بنزن موجود در پلاتفرمیت پالایشگاهی مورد استفاده قرار گرفت. ارزیابی کاتالیستها در راکتور پیوسته بستر ثابت در فشار اتمسفر و محدوده دمایی K 473-423 صورت گرفت. شناسایی خصوصیات فیزیکوشیمیایی کاتالیستها توسط روشهای XRD، XRF، FESEM،EDS-map، جذب شیمیایی H2 و جذب-واجذب نیتروژن انجام شد. اثر نسبت مولی هیدروژن به بنزن و سرعت فضایی در فعالیت کاتالیست‌ها مطالعه گردید درصد پراکندگی ذرات نیکل به روش تهیه، میزان نیکل نشانده شده و برهم‌کنش بین پایه و نیکل وابسته است. کاتالیستهای تهیه شده با روش ترسیب- رسوب‌گیری و سل-ژل، بنزن موجود در پلاتفرمیت را 6-4 برابر بیشتر از تولوئن هیدروژنه می‌کنند. بالاترین تبدیل بنزن در دمای K 448 توسط کاتالیست تهیه شده با روش ترسیب-رسوب‌گیری بدست آمد. این کاتالیست به دلیل پراکندگی بیشتر و همگن ذرات نیکل عملکرد بهتری در هیدروژناسیون بنزن دارد.

کلیدواژه‌ها

عنوان مقاله [English]

Study of the Effect of Catalyst Preparation Method on Benzene Reduction in the Refinery Platformate Using Competitive Hydrogenation

نویسندگان [English]

  • Taghi Rostamikia 1
  • Mohammad Hassan Peyrovi 2
  • Hoda Farajollahi 3
1 Shahid Beheshti University
2 professor of Shahid Beheshti university/ chemistry department
3 National Iranian Oil Refinery and Distribution Company
چکیده [English]

Nickel catalysts were prepared with different methods and used for hydrogenation of benzene in the refinery platformate. The catalysts were evaluated in a continuous fixed-bed reactor at atmospheric pressure and temperature range of 473-423 K. The physicochemical properties of catalysts were identified by XRD, XRF, FESEM, EDS-map, H2 adsorption and nitrogen adsorption/desorption methods. The effect of hydrogen to benzene ratio and space velocity on catalysts activity were studied. The percentage of nickel particles dispersion is dependent to the method of preparation, the amount of loaded nickel and the interaction between the support and nickel. The catalysts produced by the sedimentation and sol-gel method, 4-6 times more than toluene hydrogenated benzene in the platformate. The highest benzene conversion at 448 K temperature was obtained by catalyst prepared by sedimentation. This catalyst has a better performance in the hydrogenation of benzene due to the greater dispersion and homogeneity of nickel particles.

کلیدواژه‌ها [English]

  • Competitive Hydrogenation
  • Platformate
  • Particles Size and Distribution
  • Benzene Reduction
  • Active Sites

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