Farayandno

Farayandno

Designing Deisopentanizer Columns of Isomerization Units to Increase the Octane Number of Gasoline

Document Type : Original research

Authors
1 Ph.D. Student of Chemical Engineering, Faculty of Engineering, University of Kashan, Iran
2 Assistant Professor of Chemical Engineering, Faculty of Engineering, University of Kashan, Iran
Abstract
In this research, the De-isopentanizer tower of the three selected units was designed and redesigned aiming to examine the octane number of the effluent from the De-isopentanizer tower, the isopentane recovery rate, and improving the processes of selected units. The octane number of the tower top products in reference unit and 3 are 91.5 and 91.28, respectively, and the recovery rate of isopentane in the reference units is 95.96%, and in unit 3 is 92.68%. Unit 2 has an octane number and recovery of 85 and 75.24%, respectively, which is the lowest among all. By carrying out the retrofit in Units 2 and 3, a new process was achieved. A cost analysis of the De-isopentanizer towers designed for units 2 and 3 and the simulated tower for the reference unit showed that the fixed, operating, utility, and total costs of the reference unit were higher than the others.
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[1] Z. Ghazizahedi, M. Hayati-Ashtiani, "Retrofitting Isomerization Process to Increase Gasoline Quality and Decrease CO2 Emission along with Energy Analysis Using Pinch Technology", Energy Sources Part A: Recovery, Utilization, and Environmental Effects, vol. 47, pp. 3778-3789, 2025.
[2] Sh. Mojoodi, M. Hayati-Ashtiani, "Investigating the Reactor Section of the Production Process of Tissue Plasminogen Activator Using Simulation", Iranian Chemical Engineering Journal, vol. 24, pp. 79-108, In Persian, 2025.
[3] S. Barzegar, M. Hayati-Ashtiani, "Studying and Simulating the Separation Process of the Production Unit of Tissue Plasminogen Activator", Iranian Chemical Engineering Journal, vol 23, pp. 20-29, In Persian, 2024.
[4] A. Vukovic, "Reactor Temperature Optimization of the Light Naphtha Isomerization Unit", Goriva i Maziva (Fuels and Lubricants), vol. 53, pp. 195-206, 2013.
[5] D.K. Sullivan, Handbook of Petroleum Refining Processes, 3rd Edition, McGraw-Hill, 2004.
[6] W.S. Osman, A.E. Fadel, S.M. Salem, A.M. Shoaib, A.G. Gadallah, A.A. Bhran, "Optimum Design of Naphtha Recycle Isomerization Unit with Modification by Adding De-Isopentanizer", Processes, vol. 11, 3406, 2023.
[7] A.T. Jarullah, F.M. Abed, A.M. Ahmed, I.M. Mujtaba, "Optimization of Several Industrial and Recently Developed AJAM Naphtha Isomerization Processes Using Model Based Techniques", Computers, vol. 126, pp. 403–420, 2019.
[8] N. Viswanadham, S.K. Saxena, M. Garg, Octane number enhancement studies of naphtha over noble metal loaded zeolite catalysts. Journal of Industrial and Engineering Chememisttry, vol. 19, pp. 950–955, 2013.
[9] M.V. Maylin, M.V. Kirgina, E.V. Sviridova, B.V. Sakhnevitch, E.D. Ivanchina, "Calculation of Gasoline Octane Numbers Taking into Account the Reaction Interaction of Blend Components", Procedia Chemistry, vol. 10, pp. 477-484, 2014.
[10] W. L. Nelson, Petroleum Refinery Engineering, 4th Edition: McGraw-Hill, 1958.
[11] S. Parkash, Refining Processes Handbooks. Gulf Publishing Company, Houston, 2004.