نشریه علمی فرآیند نو

نشریه علمی فرآیند نو

مطالعه و رتبه‌بندی روش‌های تولید 2،5- فوراندی کربوکسیلیک اسید با بکارگیری فرایند تحلیل سلسله مراتبی

نوع مقاله : پژوهشی

نویسندگان
1 پالایشگاه نفت ستاره خلیج فارس، بندرعباس، ایران
2 گروه آموزشی مهندسی شیمی، دانشکده فنی، دانشگاه مراغه
3 دانشجوی کارشناسی ارشد مهندسی شیمی، دانشگاه مراغه، مراغه، ایران
4 دانشیار گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه مراغه، مراغه، ایران
چکیده
صنایع شیمیایی در سال­های اخیر به­دنبال شناسایی منابع تجدید­پذیر مشتق شده از زیست­توده می­باشند تا وابستگی به منابع فسیلی، آلودگی ناشی از آن و انتشار دی­اکسیدکربن را کاهش دهند. 2،5-فوراندی کربوکسیلیک اسید یکی از بلوک­های سازنده مرتبط کننده زیست توده به مواد شیمیایی باارزش افزوده است. اکسیداسیون ۵-هیدروکسی متیل فورفورال سبب تولید 2،5-فوراندی کربوکسیلیک اسید می­شود که از آن مونومر با ارزش به نام پلی­اتیلن­فورانوات تشکیل می­گردد که به­عنوان جایگزینی برای پلی­اتیلن­ترفتالات استفاده می­شود. در این مطالعه، هدف اصلی انتخاب بهترین رویه برای تولید FDCA با به­کارگیری فرآیند تحلیل سلسله مراتبی می­باشد. پارامتر های توجیه اقتصادی، زیست­محیطی، فنی، اجتماعی و قابلیت اطمینان به­ عنوان معیار معرفی گردید و همچنین روش­های اکسیداسیون، کاتالیزوری و بیولوژیکی گزینه­های این مقایسات محسوب می­شوند. در این مطالعات مقایساتی بین معیار­ها، زیر معیار­ها و گزینه­ها صورت گرفت که روش بیولوژیکی با ۵۲ درصد و معیار اقتصادی با 47/1 درصد در اولویت قرار گرفت.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Studying and Ranking Production Methods of 2,5-Furan dicarboxylic acid by Implementing the Analytical Hierarchy Process (AHP)

نویسندگان English

hasan rajabi 1
Asadollah Karimi 2
elham khalajkarimi 3
siamak alipour 4
1 Persian Gulf Star Oil Refinery, BandarAbbas, Iran
2 Department of Chemical Engineering, University of Maragheh, Maragheh, Iran
3 M. Sc student of Chemical Engineering, University of Maragheh, Maragheh, Iran
4 Associate Professor, Chemical Engineering Department, Faculty of Engineering, University of Maragheh, Maragheh, Iran
چکیده English

In recent years, chemical industries have sought to identify renewable resources derived from biomass in order to reduce dependence on fossil resources, decreasing the resulting pollution and carbon dioxide emissions. 2,5-furandicarboxylic acid (FDCA) is one of the building blocks that connects biomass conversion to value added chemicals. Oxidation of 5-hydroxymethylfurfural produces the FDCA, from which a valuable monomer namely polyethylene furanoate can be synthesized, which is an alternative to polyethylene terephthalate. In this study, the main goal is to choose the best procedure for producing FDCA by implementing the Analytical Hierarchical Process (AHP). The AHP was performed by selecting economic, environmental, technical, social and reliability justification as criteria, and oxidation, catalytic and biological methods were considered as alternatives for these comparisons. In these studies, comparisons were made between the criteria, sub-criteria and alternatives. Thus, the biological method was prioritized with 52% and the economic criterion with 47.1%.

کلیدواژه‌ها English

2
5-Furan Dicarboxylic Acid (FDCA)
Analytical Hierarchical Process (AHP)
5-Hydroxymethylfurfural (5-HMF)
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