جداسازی ترکیب نیتروژن‌دار کینولین از گازوئیل با استفاده از چارچوب‌های آلی – فلزی

نوع مقاله : ترویجی

نویسندگان

1 دانشکده مهندسی شیمی، دانشگاه صنعتی امیرکبیر، تهران ، ایران

2 دانشیار دانشکده مهندسی شیمی، دانشگاه صنعتی امیرکبیر

3 شرکت پژوهش و فن‌آوری، شرکت ملی پتروشیمی ایران

4 شرکت ملی پالایش و پخش

چکیده

با توجه به اثرات زیست‌محیطی نشر ترکیبات NOx و اثرات منفی ترکیبات نیتروژن‌دار (NCCs) بر فرآیند گوگردزدایی هیدروژنی (HDS)، فرآیند نیتروژن‌زدایی با جذب سطحی (ADN) قبل از HDS اهمیت بسیار زیادی پیدا کرده است. چارچوب‌های آلی-فلزی (MOFs) دسته جدید از جاذب‌ها هستند که کارایی آن‌ها در فرآیند ADN توسط پژوهشگران مطالعه شده است. هدف این مقاله، مقایسه نتایج جذب تک‌جزیی کینولین و جذب رقابتی کینولین/دی‌بنزوتیوفن بر روی جاذب‌های OPA-1 وOPA-2 (ترکیبات با پایه MIL-100 و MIL-101) است. آزمون‌های XRD، FTIR و BET برای مشخصه‌یابی نمونه‌های تولیدی استفاده شدند. براساس مطالعات سینتیکی و تعادلی مشخص شد که سینتیک شبه مرتبه اول و ایزوترم لانگمیر دقت مناسبی در تخمین داده‌های تجربی دارند. از میان جاذب‌ها OPA-2 با بیشینه ظرفیت جذب mgN/g ads 91/49 و گزینش‌پذیری 24/58 بهترین عملکرد را دارد. در آزمایش‌های جذب ترکیبات نیتروژن‌دار از نمونه صنعتی مشخص شد که ظرفیت و گزینش‌پذیری جذب OPA-2 به ترتیب mgN/gads 14/65 و 17/96 است.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Separation of quinolone as nitrogen containing compound from diesel using metal organic frameworks

نویسندگان [English]

  • Mohamad Songolzadeh 1
  • mansooreh Soleimani 2
  • Maryam Takht Ravanchi 3
  • mahdi Dejhosseini 4
1 Chemical Engineering, Amirkabir University of Technology, Tehran, Iran
2 Department of Chemical Engineering, Amirkabir University of Technology (Tehran polytechnic)
3 Petrochemical Research and Technology Company, National Petrochemical Company
4 National Iranian Oil Refining and Distribution Company
چکیده [English]

Regarding environmental effects of NOx emission and negative effects of nitrogen containing compounds (NCCs) on the performance of hydrogen desulfurization (HDS) process, adsorptive denitrogenization (ADN) before HDS process is very important. Metal organic frameworks (MOFs) are a new adsorbent group, which is highly studied for AND process. The goal of this paper is to compare quinolone (QUI) adsorption capacity and QUI/ dibenzothiophene (DBT) selectivity on the OPA-1 and OPA-2 adsorbents (based on the MIL-100 and MIL-101, respectively). These adsorbents were characterized by XRD, FTIR and specific surface area (BET). Isotherm and kinetic studies indicated that the Langmuir isotherm and pseudo-first-order model can successfully describe the experimental data. Among the studied adsorbents, OPA-2 with maximum adsorption capacity equal 91.49 mgN/gads and QUI/DBT selectivity equal 24.56 had the best performance for QUI selective adsorption. The adsorption capacity and selectivity for removal NCCs from industrial sample were 14.65 mgN/gads and 17.69, respectively.

کلیدواژه‌ها [English]

  • Nitrogen Containing Compounds
  • Adsorptive Denitrogenization
  • Metal Organic Frameworks (MOFs)
  • Quinolone
  • Dibenzothiophene

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نشریه علمی فرآیند نو
دوره 14، شماره 66
شهریور 1398
صفحه 36-55

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