ارزیابی انرژی و اکسرژی فرآیند تولید هیدروژن از تشکیل مجدد بخار گلیسرول جهت بهبود عملکرد

نوع مقاله : پژوهشی

نویسندگان

1 پتروشیمی لرستان، خرم آباد، لرستان، ایران

2 شرکت ملی گاز ایران (NIGC)، مجتمع گاز پارس جنوبی (SPGC)، عسلویه، ایران

3 آزمایشگاه نانوتکنولوژی ، دانشکده فنی دانشگاه تهران ، تهران ، ایران

4 گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه یاسوج، یاسوج، ایران

5 دپارتمان مهندسی فرآیند، دانشکده مهندسی شیمی ، دانشگاه تربیت مدرس تهران، ایران

چکیده

در این مطالعه تولید هیدروژن از ریفرمینگ بخار گلیسرول (GSR) به عنوان منبع تجدیدپذیر انرژی مورد بررسی قرار گرفته است. برای همه نقاط، شبیه­سازی موازنه مربوط به اکسرژی صورت گرفت و شدت انتشار کربن ‌دی‌اکسید و شدت تولید هیدروژن نیز برای فرآیند ارائه شده، محاسبه گردید. نتایج شبیه­سازی نشان دادند که شدت تولید هیدروژن در فرآیند GSR برابر با  3/92 بوده که در مقایسه با فرآیندهای متداول در جایگاه خوبی قرار دارد. تحلیل اکسرژی نشان داد که کل تخریب اکسرژی فرآیند GSR معادل با 24755/871 کیلووات است که در این بین، ریفرمر بخار گلیسرول با سهم 97/18 درصدی دارای بالاترین میزان تخریب اکسرژی است. براساس ارزیابی زیست محیطی، در مجموع از فرآیند GSR معادل با 24/45 تن در ساعت کربن ‌دی‌اکسید منتشر می­شود که سهم انتشار برای جریان­های فرآیندی، امکانات و تسهیلات فرآیندی و خوراک به ترتیب 96/59، 3/414 و صفر درصد است.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Evaluation of Energy and Exergy of Hydrogen Production Process from Glycerol Steam Reformation to Improve Performance

نویسندگان [English]

  • Ehsan Jafarian 1
  • Morteza Afkhamipour 2
  • Hamid Safarzadeh 3
  • Parviz Darvishi 4
  • mohammad shamsi 5
1 Lorestan Petrochemical,, Khorram Abad,, Lorestan, Iran
2 National Iranian Gas Company (NIGC), South Pars Gas Complex (SPGC), Asalouye, Iran
3 Nanotechnology Laboratory, Faculty of Engineering, University of Tehran, Tehran, Iran
4 Chemical Engineering Department, School of Engineering, Yasuoj University, Yasuj, Iran
5 Process Engineering Department, Tarbiat Modares University, Tehran, Iran
چکیده [English]

In this study, hydrogen production from glycerol steam reforming (GSR) has been investigated as a renewable source of energy. Exergy-related balance was done for all simulation points, and carbon dioxide emission intensity and hydrogen production intensity were also calculated for the presented process. The simulation results showed that the hydrogen production intensity in the GSR process was equal to 3.92 kmole H2/kmole feed, which is in a good place compared to conventional processes. Exergy analysis showed that the total exergy destruction of the GSR process is equal to 24755.871 kW, among which, the glycerol steam reformer has the highest exergy destruction rate with a share of 97.18%. Based on the environmental assessment, in total, the GSR process emits carbon dioxide equivalent to 24.45 tons/h, and the share of emissions for process flows, utility and feed is 96.59, 3.414 and 0.00 percent, respectively.

کلیدواژه‌ها [English]

  • Hydrogen Production
  • Glycerol Vapor Reforming
  • Energy Analysis
  • Exergy
  • Process Performance Improvement

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